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Change the Windows Explorer Default Startup Folder
To change the default startup folder for Windows Explorer:

  1. Click Start, point to All Programs, point to Accessories, and then right-click Windows Explorer.
  2. On the menu that appears, click Properties.
  3. In the Target box, append the "/root" command-line switch to the "%SystemRoot%\Explorer.exe" command, using the startup location that you want. For example, if you want Windows Explorer to start at the root of drive C, edit the command to the following:
      %SystemRoot%\Explorer.exe /root, C:\
  4. Click OK.